Response to Comment on "Cycling Li-O₂ batteries via LiOH formation and decomposition".
نویسندگان
چکیده
We described a lithium-oxygen (Li-O2) battery comprising a graphene electrode, a dimethoxyethane-based electrolyte, and H2O and lithium iodide (LiI) additives, lithium hydroxide (LiOH) being the predominant discharge product. We demonstrate, in contrast to the work of Shen et al., that the chemical reactivity between LiOH and the triiodide ion (I3 (-)) to form IO3 (-) indicates that LiOH can be removed on charging; the electrodes do not clog, even after multiple cycles, confirming that solid products are reversibly removed.
منابع مشابه
Comment on "Cycling Li-O₂ batteries via LiOH formation and decomposition".
Based on a simple thermodynamic analysis, we show that iodide-mediated electrochemical decomposition of lithium hydroxide (LiOH) likely occurs through a different mechanism than that proposed by Liu et al (Research Article, 30 October 2015, p. 530). The mismatch in thermodynamic potentials for iodide/triiodide (I(-)/I3 (-)) redox and O2 evolution from LiOH implies a different active iodine/oxyg...
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ورودعنوان ژورنال:
- Science
دوره 352 6286 شماره
صفحات -
تاریخ انتشار 2016